Enantioselective Friedel-Crafts Alkylation Reaction of Indoles with α-Trifluoromethylated-β-nitrostyrenes Catalyzed by Chiral BINOL Metal Phosphate
nantioselective Friedel-Crafts Alkylation Reaction of Heteroarenes with N-Unprotected Trifluoromethyl Ketimines by Means of Chiral Phosphoric Acid
Miyagawa, M.; Yoshida, M.; Kiyota, Y.; Akiyama, T. Chem. Eur. J.2019, 25, 5677-5681.
Diastereoselective Synthesis of CF3-substituted Spiroisochromans by [1,5]-Hydride Shift/Cyclization/Intramolecular Friedel-Crafts Reaction Sequence
Reduction of Nitroarenes to Anilines with Benzothiazoline: Application to Enantioselective Synthesis of 2-Arylquinoline Derivatives
Miyagawa, M.; Yamamoto, R.;Kobayashi, N.; Akiyama, T. Synlett 2019, 30, 499-502.
Ligand-Free Trifluoromethylation of Iodoarenes by Use of 2-Aryl-2-trifluoromethylbenzimidazoline as New Trifluoromethylating Reagent
Miyagawa,M.; Ishikawa, T.; Shinkai, K.; Akiyama, T. J. Fluorine Chem.2019, 219, 29-31.
Highly Diastereoselective Synthesis of Tricyclic Fused-Pyrans by Sequential Hydride Shift Mediated Double C(sp3)–H Bond Functionalization
Mori, K.; Umehara, N.; Akiyama, T. Chem. Sci. 2018, 9, 7327-7331.
Chiral Magnesium Bisphosphate Catalyzed Asymmetric Double C(sp3)–H Bond Functionalization Based on Sequential Hydride Shift/Cyclization Process
Mori, K.; Isogai, R.; Kamei, Y.; Yamanaka, M.; Akiyama, T. J. Am. Chem. Soc.2018, 140, 6203-6207.
Asymmetric Reduction of Trifluoromethyl Alkynyl Ketimines by Chiral Phosphoric Acid and Benzothiazoline
Miyagawa, M.; Takashima, K.; Akiyama, T. Synlett.2018, 29, 1607-1610.
Cooperative Catalysis with Coupled Chiral Induction in 1,3-Dipolar Cycloadditions of Azomethine Ylides, Cayuelas, A.; Olatz Larrañaga
Tishchenko Reaction Using Substoichiometric Amount of Metallic Zinc
Niobium(V)-Catalyzed Defluorinative Triallylation of α,α,α-Trifluorotoluene Derivatives by Triple C-F Bond Activation
Saito, K.; Umi, T.; Yamada, T.; Suga, T. Akiyama, T. Og. Biomol. Chem. 2017, 15, 1767-1770.
Highly Efficient Kinetic Resolution of PHANOL by Chiral Phosphoric Acid Catalyzed Asymmetric Acylation
Mori, K.; Kishi, H.; Akiyama, T. Synthesis, 2017, 49, 365-370.
Versatile and highly efficient oxidative C(sp3)–H bond functionalization of tetrahydroisoquinoline promoted by bifunctional diethyl azodicarboxylate (DEAD): scope and mechanistic insights
Suga, T.; Iizuka, S.; Akiyama, T. Org. Chem. Front. 2016, 3, 1259-1264.
Enantiodivergent Atroposelective Synthesis of Chiral Biaryls by Asymmetric Transfer Hydrogenation: Chiral Phosphoric Acid Catalyzed Dynamic Kinetic Resolution
Mori, K.; Itakura, T.; Akiyama, T. Angew. Chem. Int. Ed. 2016, 55, 11642-11646.
Dynamic Kinetic Resolution Approach for the Asymmetric Synthesis of Tetrahydrobenzodiazepines Using Transfer Hydrogenation by Chiral Phosphoric Acid
Horiguchi, K.; Yamamoto, E.; Saito, K.; Yamanaka, M.; Akiyama, T. Chem. Eur. J. 2016, 22, 8078–8083.