Cluster Preface: BINOL Phosphates for Chemistry
Chiral Phosphoric Acid Catalyzed Kinetic Resolution of Indolines Based on a Self-Redox Reaction
Saito. K.; Akiyama, T. Angew. Chem. Int. Ed. 2016 55, 3148-3152.
Why Benzothiazoline Cannot Be as Effective as Hantzsch Ester as a Hydrogen Donor in Chiral Phosphoric Acid-Catalyzed Asymmetric Reductive Amination of Ketones?
Kim, K.-H; Akiyama, T.; Cheon, C.-H. Chem. Asian J. 2016, 11, 274-279.
Transformation of Trifluorotoluenes Triggered by Titanium Chloride(IV) Catalyzed Hydrodefluorination Using Hydrosilanes
Yamada, T.; Saito, K.; Akiyama, T. Adv. Synth. Catal. 2016, 358, 62-66.
Chiral Phosphoric Acid Catalyzed Oxidative Kinetic Resolution of Cyclic Secondary Amine Derivatives including Tetrahydroquinolines by Hydrogen Transfer to Imines
Saito, K.; Miyashita, H.; Akiyama, T. Chem. Commun. 2015, 51, 16648-16651.
Enantioselective Synthesis of Fused Heterocycles with Contiguous Stereogenic Centers by Chiral Phosphoric Acid Catalyzed Symmetry Breaking
Mori, K.; Miyake, A.; Akiyama, T. Chem. Commun. 2015, 51, 16107-16110.
Stronger Brønsted Acids: Recent Progress
B(C6F5)3-Catalyzed Hydrodesulfurization Using Hydrosilanes – Metal-Free Reduction of Sulfides
Saito, K., Kondo, K.; Akiyama, T. Org. Lett., 2015, 17, 3366-3369.
Chiral Phosphoric Acid Catalyzed Asymmetric Synthesis of 2-Substituted 2,3-Dihydro-4-quinolones by a Protecting-Group-Free Approach
Saito, K.; Moriya, Y.; Akiyama, T. Org. Lett. 2015, 17, 3203-3205.
Synthesis of 3-Aryl-1-trifluoromethyltetrahydroisoquinolines by Bronsted Acid Catalyzed C(sp3)3)-H Bond Functionalization
Mori, K.; Umehara, N.; Akiyama, T. Adv. Synth. Catal. 2015, 357, 901-906. Front Cover and VIP article.
Benzothiazoline: Versatile Hydrogen Donor for Organocatalytic Transfer Hydrogenation
Zhu, C.; Saito, K.; Yamanaka, M.; Akiyama, T. Acc. Chem. Res. 2015, 47 , 388-398.
γ-Silylboronates in the Chiral Brønsted Acid-catalysed Allylboration of Aldehydes
Pablo, B.; Rodriguez, E.; Saito, K.; Fustero, S.; Akiyama, T. Chem. Commun. 2015, 51, 5246-5249.
Enantioselective Synthesis of Chiral Biaryl Chloride/Iodide by Chiral Phosphoric Acid Catalyzed Sequential Halogenation Strategy
Mori, K.; Kobayashi, M.; Itakura, T.; Akiyama, T. Adv. Synth. Catal. 2015, 357, 35-40.
Asymmetric Transfer Hydrogenation of Ketimines by Indoline as Recyclable Hydrogen Donor
Saito, K.; Miyashita, H.; Akiyama, T. Org. Lett. 2014, 16, 5312-5315.
Chiral Phosphoric Acid Catalyzed Transfer Hydrogenation of Ketimine Derivatives; Remarkable Difference in Enantioselectivity depending on Hydrogen donors
Saito, K.; Horiguchi, K.; Shibata, Y.; Yamanaka, M.; Akiyama, T. Chem. Eur. J. 2014, 20, 7616-7620.