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    Benzothiazolines as Radical Transfer Reagents: Hydroalkylation and Hydroacylation of Alkenes via Radical Generation under Photoirradiation Conditions

    Uchikura, T.; Moriyama, K.; Toda, M.; Mouri, T.; Ibáñez, I.; Akiyama, T. Chem. Commun. 2019, 55, 11171-11174. (Front cover)

    Enantioselective Synthesis of 1-Substituted 1,2,3,4-Tetrahydroisoquinolines via the 1,3-Dipolar Cycloaddition by Chiral Phosphoric Acid

    Jin, Y.; Honma, Y.; Miyagawa, M.; Akiyama, T. Synlett 2019, 30, 1541-1545.

    Enantioselective Friedel-Crafts Alkylation Reaction of Indoles with α-Trifluoromethylated-β-nitrostyrenes Catalyzed by Chiral BINOL Metal Phosphate

    Ibáñez, I.; Kaneko, M.; Kamei, Y.; Tsutsumi, R.; Yamanaka, M.; Akiyama, T. ACS Catal.2019, 9, 6903-6909.

    nantioselective Friedel-Crafts Alkylation Reaction of Heteroarenes with N-Unprotected Trifluoromethyl Ketimines by Means of Chiral Phosphoric Acid

    Miyagawa, M.; Yoshida, M.;  Kiyota, Y.; Akiyama, T. Chem. Eur. J.2019, 25, 5677-5681.

    Diastereoselective Synthesis of CF3-substituted Spiroisochromans by [1,5]-Hydride Shift/Cyclization/Intramolecular Friedel-Crafts Reaction Sequence

    Tamura, R.; Kitamura, E.; Tsutsumi, R.; Yamanaka, M.; Akiyama, T.; Mori, K. Org. Lett.2019, 21, 2383-2387.

    Reduction of Nitroarenes to Anilines with Benzothiazoline: Application to Enantioselective Synthesis of 2-Arylquinoline Derivatives

    Miyagawa, M.; Yamamoto, R.;Kobayashi, N.; Akiyama, T. Synlett 2019, 30, 499-502.

    Ligand-Free Trifluoromethylation of Iodoarenes by Use of 2-Aryl-2-trifluoromethylbenzimidazoline as New Trifluoromethylating Reagent

    Miyagawa,M.; Ishikawa, T.; Shinkai, K.; Akiyama, T. J. Fluorine Chem.2019, 219, 29-31.

    Highly Diastereoselective Synthesis of Tricyclic Fused-Pyrans by Sequential Hydride Shift Mediated Double C(sp3)–H Bond Functionalization

    Mori, K.; Umehara, N.; Akiyama, T. Chem. Sci. 2018, 9, 7327-7331.

    Chiral Magnesium Bisphosphate Catalyzed Asymmetric Double C(sp3)–H Bond Functionalization Based on Sequential Hydride Shift/Cyclization Process

    Mori, K.; Isogai, R.; Kamei, Y.; Yamanaka, M.; Akiyama, T. J. Am. Chem. Soc.2018, 1406203-6207.

    Asymmetric Reduction of Trifluoromethyl Alkynyl Ketimines by Chiral Phosphoric Acid and Benzothiazoline

    Miyagawa, M.; Takashima, K.; Akiyama, T. Synlett.2018, 29, 1607-1610.

    Cooperative Catalysis with Coupled Chiral Induction in 1,3-Dipolar Cycloadditions of Azomethine Ylides, Cayuelas, A.; Olatz Larrañaga

    Cayuelas, A.; Olatz Larrañaga, O.; Selva, V.; Nájera, T.; Akiyama, T.; Sansano, J.M.; de Cózar, A.; Miranda, J. I.; Cossío, F. P. Chem. Eur. J.2018, 24, 8092-8097.

    Tishchenko Reaction Using Substoichiometric Amount of Metallic Zinc

    Miyagawa, M.; Akiyama, T. Chem. Lett.2018, 47, 78-81.

    Niobium(V)-Catalyzed Defluorinative Triallylation of α,α,α-Trifluorotoluene Derivatives by Triple C-F Bond Activation

    Saito, K.; Umi, T.; Yamada, T.; Suga, T. Akiyama, T. Og. Biomol. Chem. 2017, 15, 1767-1770.

    Highly Efficient Kinetic Resolution of PHANOL by Chiral Phosphoric Acid Catalyzed Asymmetric Acylation

    Mori, K.; Kishi, H.; Akiyama, T. Synthesis, 2017, 49, 365-370.

    Versatile and highly efficient oxidative C(sp3)–H
 bond functionalization of tetrahydroisoquinoline promoted by bifunctional diethyl azodicarboxylate (DEAD): scope and mechanistic insights

    Suga, T.; Iizuka, S.; Akiyama, T. Org. Chem. Front. 2016, 3, 1259-1264.

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